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Cost-effective spinel cathode material with high rate capability and long cycle stability
The Cell Lab Lithium Manganese Oxide (LiMn₂O₄, LMO) spinel powder is a reliable, cobalt-free cathode material for lithium-ion batteries, offering excellent electrochemical stability and rate performance.
With a three-dimensional spinel framework, LMO supports rapid lithium-ion transport and structural robustness, making it ideal for high-rate charge/discharge applications in both research and production environments.
As one of the most cost-efficient and sustainable cathode options, LiMn₂O₄ combines high discharge capacity, long cycle life, and thermal stability, making it suitable for coin cells, cylindrical cells, power tools, and ESS systems.
3D Spinel Framework – Enables fast lithium-ion diffusion pathways for high-rate charge and discharge.
Cobalt-Free Composition – Reduces material cost and improves environmental sustainability.
High Initial Capacity – Provides >115 mAh/g, typically achieving ~122 mAh/g in coin cell testing.
Excellent Structural Stability – Maintains strong crystal integrity and low Mn dissolution during cycling.
Low Moisture & High Purity – Ensures consistent electrochemical performance and long-term storage stability.
| Property | Value |
|---|---|
| Chemical Formula | LiMn₂O₄ |
| CAS Number | 12057-17-9 |
| Formula Weight | 180.81 g/mol |
| Appearance | Grey-black spinel powder |
| Mn Content | 55.6 – 59.0 wt% |
| Particle Size (D10 / D50 / D90) | 2.5 µm / 11–17 µm (typ. 14 µm) / 35 µm |
| Purity | > 99 % |
| Tap Density | 2.0 – 2.4 g/cm³ |
| BET Specific Surface Area | 0.4 – 1.0 m²/g |
| pH | 8 – 11 |
| Moisture | < 1000 ppm |
| First Discharge Capacity | > 115 mAh/g (typ. 122 mAh/g, coin cell) |
Lithium-Ion Batteries (3.7 V Class) – Ideal for commercial and research-grade cell development.
Electric Vehicles & Power Tools – Provides high rate performance and thermal stability.
Energy Storage Systems (ESS) – Suitable for large-scale, long-life stationary storage.
Coin & Cylindrical Cells – Commonly used in laboratory-scale and pilot-line cell assembly.
Cobalt-Free Battery Research – Sustainable cathode solution for next-generation energy systems.
Q1: What are the advantages of LiMn₂O₄ compared to NMC or NCA?
A: LiMn₂O₄ offers lower cost, cobalt-free composition, and excellent safety, though with slightly lower specific capacity.
Q2: What voltage range does LiMn₂O₄ operate within?
A: It typically operates between 3.0 V and 4.3 V vs Li/Li⁺, with a voltage plateau around 4.1 V.
Q3: How does particle size affect its electrochemical behaviour?
A: The optimised D50 of ~14 µm provides a balance between electrode uniformity and ionic diffusion speed, ideal for high-rate cycling.
Q4: Is this powder suitable for aqueous processing?
A: Yes, its moderate surface area and stable spinel structure make it compatible with aqueous binder systems.
Q5: What precautions should be taken for long-term storage?
A: Store in a dry, inert environment (Ar or N₂) below 30 °C, away from moisture and CO₂ exposure.
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